By A. C. Knipe
Organic response Mechanisms 2010, the forty sixth annual quantity during this hugely profitable and detailed sequence, surveys learn on natural response mechanisms defined within the to be had literature dated 2010. It info the most recent development in quite a lot of periods of natural response mechanisms, together with reactions of alternative compounds and acids and their derivatives, oxidation and aid, aliphatic substitutions, removing reactions, and molecular rearrangements, to call a number of. An skilled staff of authors compiled those stories, making sure the standard of choice and presentation.Content:
Chapter 1 Reactions of Aldehydes and Ketones and their Derivatives (pages 1–54): B. A. Murray
Chapter 2 Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives (pages 55–78): C. T. Bedford
Chapter three Oxidation and aid (pages 79–154): ok. ok. Banerji
Chapter four Carbenes and Nitrenes (pages 155–174): E. Gras
Chapter five Nucleophilic fragrant Substitution (pages 175–190): M. R. Crampton
Chapter 6 Electrophilic fragrant Substitution (pages 191–212): M. R. Crampton
Chapter 7 Carbocations (pages 213–228): R. A. McClelland
Chapter eight Nucleophilic Aliphatic Substitution (pages 229–264): ok. C. Westaway
Chapter nine Carbanions and Electrophilic Aliphatic Substitution (pages 265–284): M. L. Birsa
Chapter 10 removing Reactions (pages 285–297): M. L. Birsa
Chapter eleven Addition Reactions: Polar Addition (pages 299–362): P. Kocovsky
Chapter 12 Addition Reactions: Cycloaddition (pages 363–392): N. Dennis
Chapter thirteen Molecular Rearrangements: half 1. Pericyclic Reactions (pages 393–417): J. M. Coxon
Chapter 14 Molecular Rearrangements: half 2. different Reactions (pages 419–456): A. Brandi and M. Gensini
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Extra resources for Organic Reaction Mechanisms · 2010: An Annual Survey Covering the Literature Dated January to December 2010
Sample text
352 An unusual reversal of the configuration of the product was observed in the case of tropylium cation. 353 Kinetic isotope effects, Hammett plots, and competition studies all point to an SN 1 mechanism. 359 A useful preferential activation of a C−F bond over a C−I bond has been achieved, reacting trifluoromethyl iodide with the lithium enolate of an α-substituted carbonyl compound. 361 Magnesium is proposed to coordinate the ketoesters and the peptidomimetic, with remote groups in the latter stereomodulating the reaction.
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