By Wolfgang H. Binder
This self-contained reference, written through a workforce of well known foreign authors undertake a didactical method of systematically conceal all vital points of designing self-healing polymers from innovations to purposes - shifting classes learnt from nature to fabrics science.
It is the 1st to debate the chemical and actual strategies for self-healing polymers, together with facets of biomimetic methods of therapeutic in nature and tissue regeneration.
Chapters will conceal the layout of self-healing polymers and clarify the dynamics in those systems.
Different self-healing techniques corresponding to encapsulated structures and supramolecular structures also are integrated, with research and friction detection in self-healing polymers and on functions rounding off the whole.
Content:
Chapter 1 rules of Self?Healing Polymers (pages 5–60): Diana Dohler, Philipp Michael and Wolfgang Binder
Chapter 2 Self?Healing in vegetation as Bio?Inspiration for Self?Repairing Polymers (pages 61–89): Thomas Speck, Rolf Mulhaupt and Olga Speck
Chapter three Modeling Self?Healing approaches in Polymers: From Nanogels to Nanoparticle?Filled Microcapsules (pages 91–111): German V. Kolmakov, Isaac G. Salib and Anna C. Balazs
Chapter four constitution and Dynamics of Polymer Chains (pages 113–137): Ana Rita Bras, Wim Pyckhout?Hintzen, Andreas Wischnewski and Dieter Richter
Chapter five actual Chemistry of Cross?Linking techniques in Self?Healing fabrics (pages 139–151): Joerg Kressler and Hans?Werner Kammer
Chapter 6 Thermally Remendable Polymers (pages 153–171): Tom Engel and Guido Kickelbick
Chapter 7 Photochemically Remendable Polymers (pages 173–191): Jun Ling, Ming Qiu Zhang and Min Zhi Rong
Chapter eight Mechanophores for Self?Healing purposes (pages 193–214): Charles E. Diesendruck and Jeffrey S. Moore
Chapter nine Chemistry of Crosslinking strategies for Self?Healing Polymers (pages 215–246): Roberto F. A. Teixeira, Xander ok. D. Hillewaere, Stijn Billiet and Filip E. Du Prez
Chapter 10 training of Nanocapsules and Core–Shell Nanofibers for Extrinsic Self?Healing fabrics (pages 247–271): Daniel Crespy and Yi Zhao
Chapter eleven Self?Healing Polymers through Supramolecular, Hydrogen?Bonded Networks (pages 273–300): Florian Herbst and Wolfgang H. Binder
Chapter 12 Metal?Complex?Based Self?Healing Polymers (pages 301–314): Stefan Bode, Benedict Sandmann, Martin D. Hager and Ulrich S. Schubert
Chapter thirteen Self?Healing Ionomers (pages 315–334): Nico Hohlbein, Max von Tapavicza, Anke Nellesen and Annette M. Schmidt
Chapter 14 the way to visual display unit and Quantify (Self?) therapeutic in Polymers and Polymer structures (pages 335–359): Ranjita okay. Bose, Ugo Lafont, Jesus M. Vega, Santiago J. Garcia and Sybrand van der Zwaag
Chapter 15 Self?Healing Epoxies and Their Composites (pages 361–380): Henghua Jin, Kevin R. Hart, Anthony M. Coppola, Ryan C. Gergely, Jeffrey S. Moore, Nancy R. Sottos and Scott R. White
Chapter sixteen Self?Healing Coatings (pages 381–399): Dmitry G. Shchukin, Dimitriya Borisova and Helmuth Mohwald
Chapter 17 program of Self?Healing fabrics in Aerospace Engineering (pages 401–412): Liberata Guadagno, Marialuigia Raimondo, Carlo Naddeo and Pasquale Longo
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Extra resources for Self-Healing Polymers: From Principles to Applications
Sample text
Pursuing this approach, new macromolecules with easier and more selective cleavable bonds were designed. 4 entry 3). In a similar approach a poly(phenylene ether) (PPE) chain can be cut by an external force as well as by heat or light. 7 Overview of mechanochemically induced self-healing systems. (a) The generation of radicals by polymer chain scission and the subsequent recombination, (b) the generation of reactive species by cleaving of highly strained ring systems under b(i) chain scission or b(ii) via subsequent pericyclic rearrangement, and (c) the mechanochemical activation of catalysts.
2 entry 17). For example, a poly(alkoxyamine ester) was developed which is able to undergo a reversible radical exchange reaction at 60 °C by homolytic cleavage of the C–O bond [147]. Thus, these systems reduced the destructive stress within the polymeric material and are potentially suitable for self-healing applications. 5j). In contrast to the previously discussed reversible self-healing concepts which are, at least theoretically, infinitely repeatable, polycondensations are limited in the number 28 1 Principles of Self-Healing Polymers of healing cycles due to the consumption of functional groups during the selfhealing process.
Thus, supramolecular multiblock copolymers as well as thermoreversible supramolecular polymer blends with tunable properties can be created. 3 entry 5). Due to immiscibility effects phase separation into a soft, supramolecular poly(acrylate amide) matrix and a hard poly(styrene) sphere could be observed. Accordingly, the approach combines elastomeric behavior, mechanical stiffness and molecular dynamics due to reversible hydrogen bonding within grafted brushes [94]. Due to the large number of hydrogen bonds, a number of promising but still unexploited hydrogen bonds as concepts for self-healing polymers exist.