Organic Reaction Mechanisms 1979

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91,19484 (1979). , Chem. Scripta, 12,40 (1977); Chem. , 90,103085 (1979). 277 278 I Reactions of Aldehydes and Ketones and their Derivatives 25 Allen, D. , and Tuong, H. , Angew. Chem. Intermat. , 18, 633 (1979). , 1979, 3507. 301 Gazizov, T. , Pyndyk, A. , Sudarev, Y. , Podobedov, V. , Kovalenko, V. , and Pudovik, A. , Izv. Akad. NaukSSSR,Ser. , 1978,2595; Chem. , 90,86317 (1979). 302 Miller, A. , J. Org. , 44, 1931, 1934 (1979). 303 Scott, K. , Abdulla, M. , and Hussein, F. , J. Chem. ,Faraday Trans.

O The reaction of amyl and hexyl acetates with H202,catalysed by H2S04, has been followed in the range ~ O - J ~ O " the . ~ The alkaline hydrolysis of several methyl benzoates under two-phase conditions can be modestly accelerated by u l t r a ~ o u n d . 6 kJ mol-l, respectively), show that there is little difference in strain energy between the five- and six-membered lactones. 50 General base catalysis of the hydrolysis of ethyl dichloroacetate by a series of 2-substituted imidazoles, at 30" in water, has been measured ;51 steric effects are small, and 2-hydroxyalkyl substituents behave normally.

Czech. Chem. , 44,631 (1979). 286 Young, P. , and McMahon, P. , J. Am. Chem. , 101,4678 (1979). , Rev. Chim. (Bucharest), 30, 528 (1979); Chem. , 91, 156948 (1979). , Rev. Chim. (Bucharest), 29, 1022 (1978); Chem. , 90,136971 (1979). Genkina, N. , Gordeev, E. , and Suvorov, N. , Zh. Org. , 14, 1501 (1978); Chem. , 90,5655 (1979). Vasil'ev, V. , and Razumova, N. , Zh. Obshch. , 48, 1482 (1978); Chem. , 89, 179153 (1978);J . Gen. Chem. USSR,48, 1361 (1978). , van Beek, H. C. , and Heertjes, P. , Ind.

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