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Additional resources for Transition Metals for Organic Synthesis: Building Blocks and Fine Chemicals, Second Revised and Enlarged Edition
Sample text
For a recent report of similar regioselectivity with an Ir catalyst, see: R. Takeuchi, M. Kashio, Angew. , Int. Ed. Engl. 1997, 36, 263. J. R. Corte, unpublished results. B. B. : B. M. Trost, I. Fleming, L. A. Paquette), Pergamon Press, Oxford, 1991, Vol. 5, pp. 1–28. B. M. Trost, G. J. Tanoury, M. Lautens, C. Chan, D. T. MacPherson, J. Am. Chem. Soc. 1994, 116, 4255; B. M. Trost, D. L. Romero, F. Rise, J. Am. Chem. Soc. 1994, 116, 4268. B. M. Trost, J. Y. L Chung, J. Am. Chem. Soc. 1985, 107, 4586.
Lautens, Tetrahedron 1987, 43, 4817; B. M. Trost, C. A. Merlic, J. Am. Chem. Soc. 1990, 112, 9590. B. M. -H. Hung, J. Am. Chem. Soc. 1983, 105, 7757; B. M. Trost, G. B. -H. Hung, J. Am. Chem. Soc. 1987, 109, 2176; G. C. Lloyd-Jones, A. Pfaltz, Angew. , Int. Ed. Engl. 1995, 34, 462. For a recent report of similar regioselectivity with an Ir catalyst, see: R. Takeuchi, M. Kashio, Angew. , Int. Ed. Engl. 1997, 36, 263. J. R. Corte, unpublished results. B. B. : B. M. Trost, I. Fleming, L. A. Paquette), Pergamon Press, Oxford, 1991, Vol.
Lilial (fragrance) (2) Very often, selective oxidations of primary and secondary alcohols to the corresponding aldehyde and ketone can be performed (geraniol to citral via a Pt/C catalyst). Equations. (3) and (4) show two commercial reactions, emphasizing the broad approach possible in oxidation reactions: oleic acid O2 3 pelargonic acid azelaic acid RuO4 butadiene CH3 COOHaO2 3 À3 1Y4-butanediol Pd 3 4 C–C Coupling C–C coupling embraces a wide spectrum of reactions, and is one of the most important reactions in fine chemical synthesis.