By H. Fischer (auth.), H. Fischer, K.-H. Hellwege (eds.)
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Additional info for Organic N-Centered Radicals and Nitroxide Radicals
Example text
Ref. 2 6-Membered rings : derivatives of acridine, pbenoxazine, phenothiazine, and flavine 9,10-Dihydro-9,9-dimethyl-lo-acridinyl Nr. 55 Nr. 53 0 Nc54 EPR/ 300 Thermal dissociation of the corresp. 128 v, w f,>; 8 H,C 1 CH, 74Neu3 Substance Generation/ Matrix or Solvent Method/ Thermal dissociation of the corresp. hydrazine/ 1,2,4Trichlorobenzene EPR/ 430 CC,,H,,NJ’ 5,10-Dihydro-5-methyl-lO-phenazinyl Deprotonation of the corresp. radical cation/ Isopropanol EPR/ 300 CC,,H,NOl’ Dehydrogenation with air/ Ethanol EPR/ 300 CCdbNOI’ 9-Oxo-9,10-dihydro-lO-acridinyl Nr.
3’) Calculations. 38) Assignments based on calculations. 300 K). , see [71Gubl]. 41) Assignments based on calculations. / add. Ref. CmT3 73Gubl “)I 73Gub3, 71Gubl 37 1. 786 71Gub2 j’)/ 71 Gubl 37 1, 7OChil Substance C~dL,W2J’ 2,2-Bis[(l,l’-biphenyl)-Cyl]l-(2,4,6-trinitrophenyl)hydrazyl Nr. 99, R(4”)=R(4”‘)=CsH, CW&&%I’ 2,2-Bis(4-nitrophenyl)l-(2,4,6-trinitrophenyl)hydrazyl Nr. 99, R@“)=R(4”‘)=NO, CGo%N,W’ 2,2-Bis(4-methoxyphenyl)l-(2,4,6-trinitrophenyl)hydrazyl Nr. 99, R(4”)=R(4”‘)=OCH3 CWA,COVU’ 2,2-Bis(4-chlorophenyl)l-(2,4,6-trinitrophenyl)hydrazyl Nr.
96, R (2) = -CL \ N 1 W-L CC,,H,&O,SI’ l-‘(2,6-Dinitrophenyl)-2-(4,5-diphenyl2-thiazolyl)-2-phenylhydrazyl s GH, Nr. 96, ~(2) = \ I 20) -3x GH5 C~I,%N,W’ 2,2-Diphenyl-l-(2,4,6-trinitrophenyl)hydrazyl (2,2-diphenyl-1-picrylhydrazyl, DPPH) Nr. / add, Ref. Oxidation of the corresp. 592 (20) 66Ryz2/ 67El’cl Oxidation of the corresp. 033 74Fill. 169 74Ser1, 73Cusl. 73Gubl,73Gub3,73Gub4 23), 73Morl,72Misl, 71Gubl 23), 71Gub2 23), 71Korl,71Makl, 70Gubl 23), 70Mor1, 7ORyzl 24), 7OSlil,69Chil, 69Erol,69Fed2 25), 69Furl,69Hegl 23), 69Heg2 23), 69Vanl,68Brol, 68Han1, 67Turl.