Chemistry of Heterocyclic Compounds: Pyrroles, Part One: The by Richard A. Jones

By Richard A. Jones

Actual and Theoretical features of 1H-Pyrroles (D. Chadwick).

The Synthesis of 1H-Pyrroles (G. Bean).

Reactivity of the 1H-Pyrrole Ring process (A. Jackson, et al.).

actual and Theoretical facets, Synthesis, and Chemical Reactivity of 2H- and 3H-Pyrroles (M. Sammes).

Index.Content:
Chapter 1 actual and Theoretical points of 1H?Pyrroles (pages 1–103): Derek J. Chadwick
Chapter 2 The Synthesis of 1H?Pyrroles (pages 105–294): Gerritt P. Bean
Chapter three Reactivity of the 1H?Pyrrole Ring method (pages 295–548): Anthony H. Jackson, Anthony H. Jackson, Marino Artico, Hugh J. Anderson, Charles E. Loader, Albert Gossauer, Petr Nesvadba and Nicholas Dennis
Chapter four actual and Theoretical facets, Synthesis, and Chemical Reactivity of 2H? and 3H?Pyrroles (pages 549–728): Michael P. Sammes

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Extra info for Chemistry of Heterocyclic Compounds: Pyrroles, Part One: The Synthesis and the Physical and Chemical Aspects of the Pyrrole Ring, Volume 48

Example text

Thus, in the aldehydes DASRIY, DASROE, DASRUK, and DIZGOI, the formyl groups are at maximum rotated out of this plane by only about 8". The crystal structure of 2,5-diformylpyrrole (DIZGOI) is interesting in that it comprises four crystallographically independent molecules that are hydrogenbonded from pyrrole nitrogen to an aldehyde oxygen atom to form a continuous chain parallel to the unit-cell b axis. Two of these molecules adopt syn, anti aldehyde conformations (21a), and two adopt the syn, syn conformation (21b); with this exception, the structural parameters for the four molecules are close.

342 The results of a detailed experimental study of the electronic spectrum of pyrrole in the vapor phase over the entire absorption region down to about 140 nm are reported in Ref. 330. 215 eV.

Tables of experimental data for m o n ~ s u b s t i t u t e dand ~ ~p~o l y s ~ b s t i t u t e dpyrroles ~ ~ ~ (see also Ref. 342 The results of a detailed experimental study of the electronic spectrum of pyrrole in the vapor phase over the entire absorption region down to about 140 nm are reported in Ref. 330. 215 eV.

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