Advances in Controlled/Living Radical Polymerization by Krzysztof Matyjaszewski

By Krzysztof Matyjaszewski

Offers new advancements in controlled/living radical polymerization in 3 components: atom move radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation move (RAFT). additionally comprises synthesis and characterization of many new materials.

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ACS Symposium Series; American Chemical Society: Washington, DC, 2003. Scheme 2. Decomposition of the photoinitiator MMMP (a-methyl-4(methylmercapto)-a-morpholino propiophenone). 7 Monomer Conversion, Χ Figure 3. Log calculated for different time ranges after a laser pulse at t = 0 for MA (circles) and DMA (squares) at 1000 bar and 40°C. 5 s (full symbols) for DMA. In Figure 4, a plot similar to the one in Figure 3 is shown for M M A (circles) and D A (squares) homopolymerizations at 40°C.

20036 ACS Symposium Series; American Chemical Society: Washington, DC, 2003. 48 The data points exhibit some cluster-type structure which is due to the slight variation OÎ/ÔMA with X that allows for deducing &,copo at (slightly) different/DMA from successive S P - P L P experiments carried out during one copolymerization experiment at increasing X. The log vs. / D M A correlation is curved for D M A - Μ Α and thus differs from the corresponding close-to-linear relation observed with the intra-family D A - M A system (dotted line in Figure 2) (6, 7).

2002, 43(2), 7. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2003. 39 3. 4. 5. ch003 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. (a) Fischer, H . Macromolecules 1997, 30, 5666. (b) Fischer, H . J. Polym. Sci. : Polym. Chem. 1999, 37, 1885. (c) Souaille, M . ; Fischer, H. Macromolecules 2000, 33, 7378. (d) Fischer, H. Chem. Rev. 2001, 101, 3581. ; Goto, M . ; Akaike, T. Macromolecules1998,31, 1064. ; Yamada, B. Macromolecules 1996, 29, 6396. ; Fukuda, T. Macromolecules 1997,30 , 4272.

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